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Chapter 6: Isomers and Stereochemistry
Quizzes
Quiz 2
Quiz 2
This activity contains 12 questions.
Which is a pair of diastereomers?
(
R,R
) and (
S,S
)
(
S,R
) and (
R,S
)
(
S,S
) and (
R,S
)
(
R,S
) and (
S,R
)
(
R,R
) and (
R,R
)
How many stereoisomers does 5-bromo-2-heptene have?
3 (one pair of enantiomers and a meso compound)
5 (two pairs of enantiomers and a meso compound)
4 (chiral pairs of cis-trans isomers)
2 (a pair of configurational isomers)
1
Which statement most closely defines the term "meso compound"?
a molecule without a plane of symmetry and with chirality centers
a molecule with a plane of symmetry and no chirality center
a molecule without a plane of symmetry and no chirality center
a molecule with a plane of symmetry and chirality centers
a substance that exists as a mixture
Which stereochemical descriptor describes the meso compound of tartaric acid [HOOCCH(OH)CH(OH)COOH]?
(2
S
,3
S
)
(3
S
)
(2
R
,3
S
)
(2
R
,3
R
)
(2
S
)
To separate enantiomers in a solution via chromatography, what material would you use as the "stationary phase"?
a solid phase that has chirality centers and is completely racemic
a solid phase that contains a single enantiomer
a solid phase that contains exactly equal amounts of enantiomers
a solid phase that contains exclusively meso compounds
a solid phase without any chiral centers
Which of the following is a pair of enantiomers?
(2
R
,3
R
)-3-chloro-2-pentanol and (2
R
,3
S
)-3-chloro-2-pentanol
(2
S
,3
R
)-3-chloro-2-pentanol and (2
R
,3
R
)-3-chloro-2-pentanol
(2
S
,3
R
)-3-chloro-2-pentanol and (2
S
,3
S
)-3-chloro-2-pentanol
(2
R
,3
S
)-3-chloro-2-pentanol and (2
S
,3
R
)-3-chloro-2-pentanol
(2
R
,3
S
)-3-chloro-2-pentanol and (2
S
,3
S
)-3-chloro-2-pentanol
Why does a racemic mixture
not
rotate plane-polarized light?
For every molecule that rotates the plane in one direction, there is a mirror image molecule that rotates the plane in the same direction.
They form opaque solutions.
For every molecule that rotates the plane in one direction, there is a mirror image molecule that rotates the plane in the opposite direction.
It contains only chiral molecules in the
S
configuration.
It contains only chiral molecules in the
R
configuration.
If an OH group were placed on each of the five carbons of pentane, how many stereoisomers would be possible for this compound and how many of these would be optically active?
7 stereoisomers; 6 would be optically active
4 stereoisomers; 2 would be optically active
4 stereoisomers; 3 would be optically active
5 isomers; 4 would be optically active
8 stereoisomers; all would be optically active
If (
R
)-2-methyl-1-butanol has a specific rotation of +5.75°, what is the specific rotation of
S
-2-methyl-1-butanol?
+5.75°
It must be experimentally determined.
-5.75°
+4.25°
0°
Which of the following is
not
a true statement?
a: Specific rotation is independent of concentration.
b: Specific rotation is independent of light path of the polarimeter.
c: Observed rotation is independent of concentration.
d: Observed rotation is independent of light path of the polarimeter.
c and d
What is the relationship between configuration and optical rotation?
R
compounds always are levorotatory.
R
compounds usually are levorotatory with few exceptions.
R
compounds usually are dextrorotatory with few exceptions.
R
compounds always are dextrorotatory.
There is no relationship.
What is the maximum number of stereoisomers possible for a compound with five chirality centers?
5
10
25
32
64
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