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Electron Delocalization and Resonance. More About Molecular Orbital Theory
Quiz 2

1 .       What is the major product obtained from the reaction of HBr with Ph-CH=CH-CH3? (Ph is a benzene ring.) [Hint]



2 .       What is the major product obtained from the reaction of HBr with Ph-CH2-CH=CH2? (Ph is a benzene ring.) [Hint]



3 .       The acidity of which of the following compounds is not affected by electron delocalization? [Hint]



4 .       Which of the following assigns the correct pKa values to phenol and cyclohexanol? [Hint]



5 .       Which of the following hydrocarbons is the most acidic? [Hint]



6 .       Which statement best describes the bonding molecular orbital of ethene? [Hint]



7 .       How many atoms in the phenolate ion share the negative charge? [Hint]



8 .       How many resonance contributors does the anilinium ion, C6H5-(+)NH3, have? [Hint]



9 .       Which carbons in the following molecule have the greatest electron density?

C(1)H2=C(2)H-C(3)H=C(4)H-NH-C(5)H=C(6)H2 [Hint]



10 .       Which of the following is the most stable resonance contributor of N2O? [Hint]



11 .       Which hydrogen atom is most easily removed from C6H5-C[Ha]2-C[Hb]2-C[Hc](C[Hd]3)-C6H5? [Hint]



12 .       Which compound contains the oxygen atom with the greatest electron density? [Hint]



13 .       Which resonance contributor contributes the most to the resonance hybrid? [Hint]



14 .       Which position in a benzylic radical has no appreciable radical character? [Hint]



15 .       How many different monosubstitution and disubstitution products would the benzene structure proposed by Ladenburg give? [Hint]



16 .       How many nodes are there (aside from the nodal plane of the p atomic orbitals) in the highest occupied molecular orbital of 1,3,5-hexatriene? [Hint]



17 .       Which of the following is not a contributing resonance structure for CH2=CH-CH=CH-.CH2? [Hint]



18 .       How many different products could be obtained in the reaction of CH2=CH-CH=CH-CH2+-CH3 with a bromide ion? [Hint]



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