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Problem Solving Center
Quiz 1

1 .       Which of the following actions will increase the degree of dissociation of formic acid in an aqueous solution nominally 0.20 M of volume 711 mL? 



2 .       Consider the titration of 25.0 mL of 0.723 M HClO4 with 0.273 M KOH. Calculate the H3O+ concentration before any KOH is added. 



3 .       What is the pH of a solution that contains an initial concentration of 0.080 M citric acid and .010 M citrate ions (Ka = 7.4 x 10-4)? 



4 .       Ka for acetic acid is 1.7 x 10-5. The pH of a buffer prepared by combining 50.0 mL 1.00 M potassium acetate and 50.0 mL 1.00 M acetic acid is 



5 .       Calculate the pH of a solution formed by mixing 20.0 mL of 0.15 M HCl with 25.0 mL of 0.12 M NaOH. 



6 .       Consider the titration of 50.0 mL of 0.217 M HN3 (Ka = 2.6 x 10-5) with 0.183 M NaOH. Calculate the pH of the solution after the addition of 29.7 mL of NaOH solution. 



7 .       Consider the following table of Ksp values:

CompoundKsp
CdS8.0 x 10-27
CuS6.3 x 10-36
PbS8.0 x 10-28
MnCO31.8 x 10-11

Which one of the compounds shown in the table is the least soluble? 



8 .       Calculate the molecular solubility of Fe(OH)3 if its Ksp equals 4.0 x 10-38



9 .       Which of the following would not be more soluble in 1.0 M HCl than in pure water? 



10 .       Calculate the molar solubility of calcium fluoride, CaF2, in a 0.050 M NaF solution. (Ignore any hydrolysis of the fluoride ion.) Ksp for CaF2 = 3.9 x 10-11



11 .       The solubility of silver carbonate is 0.032 M at 20°C. Calculate the Ksp of silver carbonate. 



12 .       Of AgCl, PbCl2, and Hg2Cl2, only _________ dissolve(s) in 6 M NH3



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