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Homework 3

1 .       What is the Ksp expression for magnesium phosphate, Mg3(PO4)2?

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2 .       If the molar solubility of CaF2 at 35°C is 1.24 x 10-3 mol/L, what is Ksp at this temperature?

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3 .       The solubility of Mg(OH)2 is 1.4 x 10-4 mol/L. Determine the Ksp for Mg(OH)2.

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4 .       If S is the solubility of a salt in moles per liter, which one of the following Ksp expressions is incorrect?

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5 .       Lead sulfate has a solubility of 4.25 mg per 100. mL of solution. What is its Ksp?

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6 .       Calculate the molar concentration of bromide ions in a saturated solution of mercury(II) bromide (Ksp = 8.0 x 10-20).

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7 .       Calculate the number of mg of silver in 250 mL of a saturated solution of Ag2CO3 (Ksp = 8.1 x 10-12).

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8 .       Calculate the solubility in mol/L of Cu(OH)2 at pH = 7.0. Ksp = 2.2 x 10-20.

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9 .       Calculate the molar solubility of calcium carbonate in 0.20 M Na2CO3 (Ksp = 2.8 x 10-9).

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10 .       Which of the following would you not expect to be more soluble in acid than in pure water?

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11 .       Ksp for AgI = 8.3 x 10-17, and Kf for Ag(CN)2- = 1.0 x 1021. Calculate the equilibrium constant for the following reaction:

AgI(s) + 2CN-(aq) Ag(CN)2-(aq) + I-(aq)

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12 .       AgCl(s) + 2NH3(aq) --> Ag(NH3)2+(aq) + Cl-(aq). Given that Kc = KspKf (where Ksp is for AgCl and Kf is for Ag(NH3)2+), the molar solubility (z) of AgCl in 2.0 M NH3 can be calculated according to which of the following equations?

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