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Cumulative Exam

1 .       Which one of the following should be the least soluble in tetrachloride, CCl4



2 .       If 200. g of a solvent is available, how many grams of a solute should be weighed out to make up a 10.0 percent solution (by mass)? 



3 .       What would be the osmotic pressure in atm produced at 25°C by a 0.0100 M NaCl solution? (Assume a van't Hoff factor of 1.87.) 



4 .       In the reaction A --> products, the initial concentration of A is 0.86 M, and 40. sec later it is 0.68 M. What is the initial rate of this reaction in M·min-1



5 .       Initial rate data were obtained for the following reaction:

A(g) + 2B(g) --> C(g) + D(g)

initialinitialinitial
Experiment[A], mol/L[B], mol/Lrate
10.150.104.5 x 10-1
20.300.101.8
30.150.209.0 x 10-1

What is the rate law for the reaction? 



6 .       Refer to the equation below, where two mechanisms are proposed for the reaction of nitrogen dioxide with carbon monoxide:

NO2(g) + CO(g) --> CO2(g) + NO(g)

Mechanism I: NO2(g) + CO(g) --> CO2(g) + NO(g) (one step)

Mechanism II: NO2(g) + NO2(g) --> NO3(g) + NO(g) (slow)

NO3(g) + CO(g) --> CO2(g) + NO2(g) (fast)

What is the predicted rate law for Mechanism I? 



7 .       What is a characteristic of the molecules that form liquid crystals? 



8 .       For the vapor-phase reaction 2AZ A2 + Z2, Keq = 16 at 523 K. If 0.030 mol AZ is introduced into a 1.00-L vessel at 523 K, then at equilibrium [Z2] is 



9 .       The value of Keq for the reaction CaCO3(s) CaO(s) + CO2(g) is 0.880 at 600°C. If a 15.0-g sample of CaCO3 is put into a 10.0-L container and heated to 600°C, what percent of the CaCO3 reacts? 



10 .       Consider the following equilibrium between oxides of nitrogen:

3NO(g) NO2(g) + N2O(g)

Using Hf(NO) = 93.37 kJ/mol, Hf(NO2) = 33.84 kJ/mol, and Hf(N2O) = 81.6 kJ/mol, calculate H for this reaction.

(i) Will the equilibrium constant for the reaction increase or decrease with increasing temperature? (ii) At constant temperature, would a change in the volume of the container affect the fraction of products in the equilibrium mixture? 



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